James McAvoy (Wanted)

Even though we've seen him in movies before, we first stood up and took notice of this Scottish hottie last year in the Academy Award-nominated film Atonement. Ever since then, we can't get enough of James' sexy Scottish brogue or his piercing blue eyes. Luckily, we won't have to wait long to see either again—James stars opposite Angelina Jolie in this summer's Wanted.